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EXPLANATION
OF TYPICAL PASSIVATION PROCEDURES
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| Passivation
is the generic term applied to procedures developed to remove the
presence of metallic (free) iron from the surface of stainless steel
products. The presence of free iron particles on the surface of stainless
steel products can cause the product to show rust spots which should
not occur with a clean or "passive" stainless steel surface.
A PASSIVE stainless steel surface would have NO free iron particles
which could potentially corrode or "rust."
During the handling
and processing operations such as forming, machining and tumbling,
particles of iron and tool steel can be embedded or smeared on the
surface of the fastener. If allowed to remain, these free iron particles
will corrode and show as rust spots.
The passivation
process involves submerging the stainless steel fastener into
a solution of nitric acid (20-25% by volume), sodium bicarbonate
(2-3% by weight) and water or 35% Nitric by volume and water
for some period of time. Twenty to thirty minutes is typical.
The nitric acid dissolves the embedded or smeared iron and
restores the original corrosion-resistant surface to the part.
It is generally
considered good practice to passivate parts after many manufacturing
processes, however in some applications it may prove unnecessary.
When the need for passivation is in doubt, testing can provide the
answer. ASTM
A380 is a recognized specification which details the specific testing
parameters to be met. Parts which pass the "Passivation Test"
per ASTM A380 have a surface void of any free iron particles. They
are considered passive.
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EXPLANATION
WITH REGARD TO PEM FASTENERS
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| Penn
Engineering typically lists Passivated and/or Tested per ASTM
A380 as it's passivation procedure. ALL parts are subjected
either to a passivation procedure OR are tested for the need for passivation.
Those parts which FAIL the passivation test are then passivated. Those
passing the test are passive and are not processed further.
For those customers
requiring that all parts are passivated and not just tested, a special
part number can be assigned and ordered.
APPLICABLE
INDUSTRY SPECIFICATIONS
- PASSIVATION
per QQ-P-35C, TYPE II or it's replacement ASTM A967
Nitric I, used as the processing spec. for passivating AISI
303, 410, 416 and 17-4PH stainless steels. Most PEM fasteners
manufactured by screw machining methods are passivated to
this specification when necessary.
- PASSIVATION
per QQ-P-35C, TYPE VI or its replacement ASTM A967, Nitric
2, Used
as the processing spec. for passivating AISI 302, 304, 305,
316, 900 stainless steel. Most PEM fasteners manufactured
by cold-heading or cold-forming methods are passivated to
this specification when necessary.
- PASSIVATION
test per ASTM A380 Used for determining if a product needs
to be passivated. Detects the presence of free iron on the surface.
Those products failing this test are then passivated by one of
the above specifications.
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